Webserver Page Instructions

I'm really struggling. I need urgent help. AppendChild seems not to work for me (see snippet below). If I remove everything the under the AppendChild instruction then the InsertAfter instruction works.

AppendChild: /configuration/system.web/profile
AppendChild: /configuration/system.web/profile/properties

InsertAfter: /configuration/system.web/compilation/assemblies/add[6]
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